Volume 316
Main Index

Issues 1-2, Pages 1-241 (25 November 1986)

Hexane-soluble complexes of alkyl- and alkenyl-sodium compounds with magnesium alkoxides Pages 1-12 Constantinos G. Screttas, Maria Micha-Screttas

Diethyl-1-magnesium chloride methanephosphonate, A novel grignard reagent and its use in organic synthesis Pages 13-18 P. Coutrot, M. Youssefi-Tabrizi, C. Grison

MgCl2 - one of the factors controlling the mechanism of the reaction between grignard reagents and titanium or zirconium tetrachloride. II Pages 19-23 Piotr Sobota, Jòzef Utko, Zofia Janas

Some reactions of phenylene-and polyphenylene-mercurials Pages 25-39 A.G. Massey, N.A.A. Al-Jabar, R.E. Humphries, G.B. Deacon

Synthesis and properties of (trifluoromethyl)trichlorosilane, a versatile precursor for CF3Si compounds Pages 41-50 H. Beckers, H. Bürger, P. Bursch, I. Ruppert

The synthesis of four-membered spiro compounds of silicon and germanium: 2,2,6,6-tetramethyl-4-metallaspiro[3.3]heptanes Pages 51-55 B.J.J. van de Heisteeg, M.A.G.M. Tinga, Y. Van den Winkel, O.S. Akkerman, F. Bickelhaupt

Über polygermane: XVII. Ph3Ge-(GePh2)3-GePh3, EIN PERGERMA-Analogon Zu n-pentan Pages 57-65 Stefan Roller, Martin Dräger

Dominant cis-diacetoxylation of alkenes with tellurium(IV) oxide and lithium bromide in acetic acid Pages 67-78 Sakae Uemura, Kouichi Ohe, Shin-ichi Fukuzawa, Suresh R. Patil, Nobuyuki Sugita

Six-coordinate molybdenum(II) complexes of 2,2′-bipyridine containing thiolate, nitrate, nitrite and pentane-2,4-dionate ligands Pages 79-84 Joseph A. Connor, E. Joyce James

Symmetrisch substituierte butadiinkomplexe von wolfram(IV) Pages 85-93 Karlheinz Stahl, Kurt Dehnicke

Dibromacetylen-komplexe von wolram(IV). die kristallstruktur von PPh4[WBr5(BrC≡CBr)]·0.5CCl4 Pages 95-104 Karlheinz Stahl, Aida El-Kholi, Ulrich Müller, Kurt Dehnicke

Unerwartete fragmentierungs-, nitrosylierungs- und hydrierungsreaktionen bei der umsetzung der metallacyclischen alkenylketonkomplexe Pages 105-119 Helmut G. Alt, Heidi I. Hayen

Schwefelmonoxid als brückenligand in zwei- und dreikern-komplexen von mangan und eisen Pages 121-138 Ingo-Peter Lorenz, Johannes Messelhäuser, Wolfgang Hiller, Michael Conrad

Synthesis gas incorporation into acylmanganese pentacarbonyls Pages 139-146 Daniel J. Sheeran, John D. Arenivar, Milton Orchin

Free radical halogenation of alkanes initiated by transition metal complexes Pages 147-162 Reg Davis, Jim L.A. Durrant, Christopher C. Rowland

Crystal and molecular structure of 2-benzylidene[3]ferrocenophane-1,3-dione Pages 163-168 E. Gyepes, T. Glowiak, Sˇ. Toma

Synthesis, crystal structure and properties of [Fe(h5-C5H5)(CO)(μ-SC5H9NCH3)]2 Pages 169-175 Walter Gaete, Josep Ros, Ramon Yan˜ez, Xavier Solans, Manuel Font-Altaba

The reaction of tricarbonyl-8-p-tolyl-8-azaheptafulveneiron with tetracyanoethene Pages 177-181 Suman K. Chopra, Patrick McArdle

A new synthetic route to mixed-metal clusters Fe2Ru(CO)12 and H2Fe2Ru2(CO)13. A crystal structure study of H2Fe2Ru2(CO)13 Pages 183-186 TapaniVenäläinen, Tapani A. Pakkanen

Cluster chemistry: LI. Reactions of some substituted ruthenium and osmium cluster carbonyls with dihydrogen. X-ray crystal structures of Ru3(μ-H)2(μ3-PPh)(CO)8(PMePh2), Ru4(μ-H)4(μ-dppm)(CO)10, Ru4(μ-H)3(μ3-PPhCH2PPh2)(CO)10 and Os3(μ-H)2(μ-dppm)(CO)8 Pages 187-211 Michael I. Bruce, Ernst Horn, Omar Bin Shawkataly, Michael R. Snow, Edward R.T. Tiekink, Michael I. Williams

“Half-open cobaltocene” chemistry: diene replacement vs. hydride abstraction by the triphenylmethyl cation Pages 213-220 Timothy D. Newbound, Richard D. Ernst

Binuclear Di-μ-hydroxo- and diμ-methoxo-pentamethylcyclopentadienyl derivatives of rhodium and iridium with pyridine type ligands. Crystal structure of [(C5Me5)Rh(py)2(μ-OH)2][CIO4]2 (py = pyridine) Pages 221-227 F.J. Lahoz, D. Carmona, L.A. Oro, M.P. Lamata, M.P. Puebla, C. Foces-Foces, F.h. Cano

Umsetzung von trisethennickel(0) mit 7,7-difluorcyclopropabenzol in gegenwart von tetraethylethylendiamin Pages 229-231 R. Benn, H. Schwager, G. Wilke

Platinum(II) trichlorostannate chemistry. On the importance of the Pt-Sn linkage in hydroformylation chemistry and a novel PtC(OSnCl2)R-carbene Pages 233-241 H.J. Ruegg, P.S. Pregosin, A. Scrivanti, L. Toniolo, C. Botteghi

Asymmetrische katalysen: XXXII. Enantioselektive phenylierung von cis-cyclohexan-1,2-diol und meso-butan-2,3-diol Pages C1-C3 Henri Brunner, Uwe Obermann, Peter Wimmer

2,6-Bis(lithiumtrimethylsilylmethyl)pyridine · 2TMEDA: A monomeric dilithio compound exhibiting electrostatic charge communication Pages C4-C8 Roland Hacker, Paul von Rague Schleyer, Gabriele Reber, Gerhard Müller, Lambert Brandsma

The synthesis and spectral properties of some highly reactive new seven-coordinate molybdenum(II) and tungsten(II) bisacetonitrile dihalogenotricarbonyl complexes: by D.K. Baker, S.G. Fraser and E.M. Keys (J. Organomet. Chem., 309 (1986) 319–321). Page C9

Schwefer(IV)-Verbindungen als Liganden. VI. Koordinative und oxidative Addition on quadratisch-planare Iridium-schwefeldioxid-Komplexe: by W.A. Schenk and J. Leissner (J. Organomet. Chem., 311 (1986) C27–C30) Page C9

Author index Page C11

Issue 3, Pages 243-375 (2 December 1986)

Siliciumverbindungen mit starken intramolekularen sterischen wechselwirkungen : XXVII. Synthese und konformation eines 2,4,6-tri-t-butylphenyl-substituierten disilans Pages C13-C16 Manfred Weidenbruch, Klaus Kramer, Siegfried Pohl, Wolfgang Saak

Author index Pages C41-C42

Topics in Organic Electrochemistry : edited by A.J. Fry and W.E. Britton, Plenum Press, New York and London, 1986, xiv + 296 pages, $49.50. ISBN 0-306-42058-9. Pages C39-C40 Kenneth R. Seddon

Photochemistry of metal---metal bonded complexes. : IV. Breaking of the metal---metal bond and decoupling of the two 1,4-diaza-1,3-butadiene (= R-DAB) fragments of bis(1-t-butylimino-2-t-butylaminoethane) (= t-Bu-IAE) during the photochemical conversion of Mo2(CO)6(t-Bu-IAE) into Mo2(CO)6(t-Bu-DAB)2 Pages C24-C28 Ronald R. Andréa, Hero E. de Jager, Derk J. Stufkens, Ad Oskam

Organometallic models for the hydrodesulphurisation (HDS) reaction: synthesis of [(η-thiophene)M(PPh3)2]+ (M = Rh, Ir) and x-ray structure of the Rh derivative, the first example of a fully characterised π-thiophene complex of an HDS-active metal Pages C35-C38 R. A. Sanchez-Delgado, R. L. Marquez-Silva, J. Puga, A. Tiripicchio and, M. Tiripicchio Camellini

Subject index Pages C43-C47

Structure and bonding characteristics of bis(2,3-dicarnomethoxynorbornadiene)dicarbonylmolybdenum and related complexes Pages C29-C34 Tahsin J. Chow, Tsi-Hsiung Lin, Shie-ming Peng, Ming-chu Cheng

An efficient one-pot synthesis of 2,5-disubstituted thiophenes from 1-propynylamines or allenic amines and thiocarbonyl compounds Pages C21-C23 R. L. P. de Jong, L. Brandsma

Organogermanium compounds: First synthesis of bioactive trithiagermatranes substituted with novel functional groups Pages C17-C20 Norihiro Kakimoto, Katsuyuki Sato, Masanao Matsui, Toyozo Takada and, Mitsuo Akiba

Fluorid-induzierte fragmentierung von acetyldimethylphenylsilan Pages 243-247 H. Zilch, R. Tacke

Reactions of vinylsilanes with ethoxycarbonylnitrene under phase-transfer conditions: A novel route to silicon-containing aziridines Pages 249-254 E. Lukevics, V. V. Dirnens, Yu. Sh. Goldberg, E. E. Liepinsh

Silylcupration of acetylenes Pages 255-260 Hsiao-Ming Chen, John P. Oliver

Tris- and tetrakis-(trifluoromethyl)fluorogermanates; the structure of an anion with pentacoordinated germanium Pages 261-269 D. J. Brauer, J. Wilke, R. Eujen

Synthesis and some reactions of a 2,2′-biphospholyl Pages 271-279 François Mercier, Serge Holand, François Mathey

Diphenylantimony(III) diphenylphosphinate and diphenylmonothiophosphinate: synthesis, spectra and crystal structure Pages 281-289 Michael J. Begley, D. Bryan Sowerby, Denise M. Wesolek, Christian Silvestru and, Ionel Haiduc

Kationische komplexe mit der bis(pentamethylcyclopentadienyl)titan(IV)-baugruppe: darstellung und struktur der dimethylformamidliganden enthaltenden komplexe [Cp*2Ti(DMF)Cl]CF3SO3 und [Cp*2Ti(DMF)2](CF3SO3)2 Pages 291-300 Brigitte Honold, Ulf Thewalt

Darstellung neuer trimethylphosphonium-salze und eines trifluoressigsäure-komplexes durch umsetzung der ylidischen metallacyclopropan-komplexe Cp′(CO)(L)HCOMe] (Cp′ = η5-C5H5, η5-C5Me5; L = CO, PMe3) mit CF3COOH. Reaktionen von [C5Me5W(CO)2(CF3COO)2][PMe3CH2CH2COMe] mit CO, PMe3, NOBF4 und Et3OBF4 Pages 301-313 Helmut G. Alt, Heidi I. Hayen

Insertion reactions of t-Bu(η5-C5H5)Fe(CO)2 Pages 315-318 Keith H. Pannell, Tony Giasolli, Ramesh N. Kapoor

Reactions of coordinated molecules : XLIX. Carbon---carbond bond formation between the donor atoms of adjacent acyl and alkenyl ligands Pages 319-323 Charles M. Lukehart, James B. Myers Jr., Brian J. Sweetman

The reactions of AgI electrophile with [Fe2(η-C5H5)2(CO)2(L){CN(Me)H}]+ and [Fe2(η-C5H5)2(CO)2{CN(Me)H}2]2+ salts (L = CO or CNMe) Pages 325-333 Brian Callan, A. R. Manning

σ versus π bonding in polymethylthiophene complexes of iron Pages 335-341 Véronique Guerchais, Didier Astruc

Preparation of IrH(diene)L2 compounds via methoxyiridium complexes: Catalysts for hydrogen transfer reactions Pages 343-349 Maria J. Fernandez, Miguel A. Esteruelas, Macarena Covarrubias, Luis A. Oro

Synthesis and reactivity of mixed pentafluorophenylpalladium(I)-platinum(I) derivatives molecular structure of ClPt(μ-dppm)2 Pd(C6F5) Pages 351-366 Juan Fornies, Francisco Martinez, Rafael Navarro, Adelaida Redondo, Milagros Tomas, Alan J. Welch

cis-Bis(7-methylnaphth-1-yl)bis(triphenylphosphan)platin(II) Pages 367-375 Hans Albert Brune, Wolfgang Schäfer, Karl-Heinz Spohn, Claus Weisemann